Material Science
Radiation Curing Enhancement by Semiconducting Nanoparticles (No. T4-2215)

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Overview

UV curing of polymers plays a critical role in technologies such as dentistry, advanced manufacturing (e.g., 3D printing), optical media production, and biotechnology. Traditional methods rely on UV irradiation of photoinitiators, but the resulting thermosets are often brittle and limited to thin, transparent formulations. This technology introduces semiconducting nanoparticles (e.g., WS₂) that generate radicals under light to initiate efficient polymerization and cross-linking, resulting in improved mechanical properties and broader applicability. Given their benign characteristics, they can be used also for reinforcing various biocompatible polymers used in medical technologies.

Applications
  • Reinforcement of radiation curing of acrylates
  • Cation-induced polymerization of epoxies for adhesives
  • Matrices for fiber composites and 3D printing resins
Differentiation
  • Enhances the mechanical properties (elasticity, yield strength, and elongation) of thermosetting polymer films
  • Increased  film fracture toughness
  • Improved film peeling resistance, strength, and adhesion
  • Accelerated photocuring process 

Electron micrographs of polyhedral nanocrystals of WS2

Development Stage

The technology has been demonstrated with dispersed tungsten disulfide fullerene-like nanoparticles (WS2-IF) in acrylate and epoxy resins photocuring, showing covalent bond formation between the nanopaticles and the matrix, resulting in improved adhesion and reduced viscosity.

Patent Status: 
European Patent Office Published: Publication Number: 4522665
Emeritus Tenne Reshef

Reshef Tenne

Faculty of Chemistry
Molecular Chemistry and Materials Science
All projects (3)
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