Material Science
Coupling of Alternating Current to Transition – Metal Catalysis (No. T4-2050)

18308
Overview

A method for coupling alternating current (AC) electrolysis to transition-metal catalysis, enabling enhanced catalytic reactions with higher yields and selectivity. 

Applications
  • Catalytic systems where one or several steps can be accelerated by electrochemical oxidation/reduction
  • Transition-metal catalytic reactions
Differentiation
  • Expanded Potentials beyond the solvent electrochemical window
  • Adjustable Selectivity
  • Innovative Stirring-free Reactor Design
  • Efficient Redox Reactions on the same electrode
  • Prevents electrode fouling 

Demonstrated setup and AC-enabled Ni-catalyzed cross-coupling reactions 

Development Stage

The method is at TRL of 4. It has been used for a variety of catalysis processes, producing different amines, aryl bromides, carboxylic acids and alcohols. 

Patent Status: 
European Patent Office Published: Publication Number: 4214355
Prof Sergey Semenov

Sergey Semenov

Faculty of Chemistry
Molecular Chemistry and Materials Science
All projects (2)
Contact for more information

Dr. Vered Pardo Yissar

Senior Director of Business Development, Exact Sciences

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