Material Science
Iron Catalyzed Ring-Opening Metathesis Polymerization (ROMP) (No. T4-1905)

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Overview

A novel iron-catalyzed Ring-Opening Metathesis Polymerization (ROMP) of olefins, which leads to several new catalytic reactions and enables the synthesis of new polymeric materials. This breakthrough replaces the costly and toxic Mo- and Ru-carbene catalysts that currently dominate olefin metathesis chemistry, using a catalyst based on earth-abundant iron.

Applications
  • New polymeric materials (i.e. Polydicyclopentadiene, Polyoxanorbornene and Cyclooctene-based polymers).
  • New engineering materials.
  • Industrial-scale production of polynorbornene using iron-based catalysts

Iron-catalyzed ROMP of norbornene

Differentiation
  • Economical
  • Bio-compatible
  • Forms high molecular weight polynorbornene
Development Status

The researchers have shown the ability to systematically perform the catalysis on a lab scale to produce Polynorbornene. 

Patent Status: 
European Patent Office Published: Publication Number: 4377007
Extension Service David Milstein

David Milstein

Faculty of Chemistry
Molecular Chemistry and Materials Science
All projects (2)
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