ClimateTech
Material Science
A Method for Lithium Recovering From Spent Lithium Iron Phosphate Batteries (No. T4-2458)

Unpublished
19403
Overview

The growing use of lithium iron phosphate (LFP) batteries creates a need for efficient recycling. Unlike Li-Co-Ni batteries, LFPs yield only lithium as a valuable metal, making acid-based methods costly and inefficient. This technology applies a scalable pyrometallurgical process: aluminum is removed with sodium carbonate, lithium carbonate is recovered via cold-water leaching after sintering, and remaining solids are smelted to produce aluminum oxide and copper ingots—without hazardous chemicals or waste.

Applications
  • Recycling of spent LFP batteries from electric vehicles and stationary energy storage systems
  • Production of battery-grade lithium carbonate for reuse in cathode manufacturing
  • Recovery of high-purity aluminum oxide and metallic copper as industrial feedstocks
  • Integration into large-scale battery recycling facilities for sustainable material supply chains
Differentiation
  • No hazardous chemicals: avoids strong acids, corrosive agents, and costly reagents
  • Multi-metal recovery – produces lithium carbonate, aluminum oxide, and copper ingots
  • Environmentally sustainable – no hazardous liquid or solid waste generated
  • Industry-ready process – based on established, scalable industrial operations

Lithium carbonate extraction yield after ice-water leaching with Me₂CO₃ excess: (1) 10% air, (2) 30% air, (3) 10% CO₂, (4) 30% CO₂.

Development Stage

Laboratory validation completed with both pure LiFePO₄ and real spent LFP batteries, achieving lithium recovery yields of 90–100% as lithium carbonate. Copper and aluminum recovered in high-purity solid forms. Next step: scale-up to a mini pilot unit (processing several kilograms of spent LFP batteries) within ~1 year, pending resources.

Full Professor Igor Lubomirsky

Igor Lubomirsky

Faculty of Chemistry
Molecular Chemistry and Materials Science
All projects (3)
Contact for more information

Dr. Vered Pardo Yissar

Senior Director of Business Development, Exact Sciences

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